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This photo has obviously been taken with the pop up flash and that'd be the first thing I'd change. Wait for daylight and stand by a large window to get a much more flattering softer, more diffuse light (vs harsh , directional pop up flash) Secondly think about the composition and apply the rul of thirds... having the main subject (the eye) slap bang in the middle is not the most interesting place to put it. There are loads of tutorials on here about composition and lighting so it's a good place to start.
Notice I've not said anything about the post processing yet as I beleieve the "solid advice for things to work on" you ask for is more basic than post processing techniques. Get the shot right first in camera. If you want to make the blue pop a bit more you can do as the other post suggests, in addition to this you need to remove the last traces of red/orange in the lower eyelid... you'll need to zoom in close to do this accurately and use a small brush. Currently the red is a small but significant distraction away from the blue. The other thing you might want to do is sharpen the image more as well, perhaps just selectively over the iris.
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