I would be one of those who would recommend GIMP its free and is powerful I wont lie it doesnt handle 16bit yet or have adjustment layers yet both are in the pipeline. Apart from that its up there with the commercial products some people dont like the dual windows but thats being fixed with a single window mode in development.
On to the thing you actually wanted to know lol Duo toning images well in the GIMP if you go to "meet the gimp" theres a video tutorial all about toning images in fact there are several all explain the whole process.
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You cant fool all of the people all of the time, some of the time all of the people will some of time but not all of the time as some of the time all of the people will some of the time but all of the people will not all of the time  !!
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