Put your camera in Aperture Priority mode, and set your aperture as wide as you can. Let the camera set the time, unless you're shooting during the day. Then it's a bit more difficult. Set your focus to infinity, and release the shutter. If you don't have a cable, utilize the self timer to avoid the shake that happens when you press the button.
Your vantage point should be one that allows you to view the storm, but not expose yourself to the lightening. So keep that in mind when setting up the shot. Generally if you can hear the thunder, you can be hit by the lightening. Not always, but it's a good thing to keep in mind.
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