I find that our cameras see stuff we often don't have the eye for. Polarizer should work as it would allow you to expose the background better and make the sky a more vibrant blue. Just make sure you use get the wb right otherwise it'll look a bit weird, at least it did in my case.
Try taking the photos at a different time of day too, mornings are best for this because the air is cooler and the smog levels are lower.
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Rebel XSi, EF-S 18-55 IS and 17-85mm IS, EF 50mm f/1.8 II, Sigma 18-250mm OS, and Speedlite 430EX II
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