I'm not a pro or anything but I did get married not to long ago. If I hired a photographer because I liked their work that I had seen but I was asking them to do something that they had never done before then I would definitely want to know. I would actually be really mad if I found out afterward.
As far as you confidence goes I would go to the location that they are having the wedding at and scope it out. See if you are allowed to take pictures there at about the same time that you would need to for the wedding so that you know exactly what you are up against. Maybe even have a friend or two come with you to pose as a bride and groom. You might want to do that for yourself and also to show the couple what you are able to capture in that setting. It could possibly make it so that they aren't even bothered by it being your first wedding shoot.
~Gonzo13
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