I agree with Dr. WooD and your wife on the other photo.
As to working with different w/b you would need to get some gels that are color balanced. Use those on your flash and set the camera accordingly if you shoot raw then don't bother adjusting camera as long as w/b is the same adjust it in pp.
As too the photo here it's a bit overexposed. The shirt is blown. Perhaps a bit darker shirt that will expose roughly the same as her face if you want. But that is just a bit picky.
For me she is leaning a bit heavy on the frame, but not much. Hopefully that pose isn't from are we done yyyyyyyyyyyyyyyeeeeeeeeeeeeeeeetttttttt????
Always have fun,
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