I'm not sure you should be thinking about it as photoshop vs. no-photoshop. You should have in your mind how you want the photo to look. If you can do it in the camera, so be it. But if you have to tweak a little in photoshop to get it perfect, you shouldn't condemn yourself. Personally, I use it as a measure of my skill with my camera. I aim to get perfect white balancing, and perfect exposure right in the camera. If I don't have to tweak anything in Photoshop...then I know I'm doing well.
I shoot in RAW, btw...so technically I have to pull everything into photoshop to convert. But you get the point.
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