Definately the third one, well balanced - the left and right looking outwards "bookending" the whole composition.
Colours look great - though I'd suggest you doubly-check the exposure - your friends nose looks very close to being blown out and lost into the background on my laptop. It's most probably my screen - but it would pay to check and tweak it if necessary before you send it for printing.
I'm sure your friend will be thrilled !
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Neil
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