I just had an afterthought. If pse is anything like PS CS4, it could be the color space you are working in. The image space itself. Go to Image>Mode>8 bit color and Image>Mode>RGB Color. If none of these work, sorry, I have no freaking idea.
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Hardware: Canon EOS Digital Rebel XTi, Kit 18-55mm, Sigma 55-200mm
Software: Mac OS X 10.5.4, Photoshop CS4 Extended, Lightroom 2, Photomatix Pro
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