Night for sure. As rdaw said, RAW can fix white balance issues.
Personally, I find that the night holds many more dazzling views. In fact, I want to get to a big city in the middle of the night at some point and get some shots from that.
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Gear: Nikon D50, Nikkor 18-70mm AF-S f/3.5-4.5, soon to get a Nikkor 50mm AF f/1.8D
Hoping to buy eventually: A long long long time from now, maybe I'll get the Nikkor 70-300mm AF-S f/4.5-5.6G VR or a Nikkor 18-200 AF-S f/3.5-5.6G VR.
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